1383941-67-0Relevant academic research and scientific papers
Synthesis and evaluation of a chiral menthol functionalized silsesquioxane: Application to diastereoselective [2+2] photocycloaddition
Yanagisawa, Yuuki,Yamaguchi, Hiroki,Nishiyama, Yasuhiro,Morimoto, Tsumoru,Kakiuchi, Kiyomi,Tabata, Kenji,Tsutsumi, Ken
, p. 101 - 110 (2013/03/13)
A novel chiral menthol derivative supported on silsesquioxane was easily synthesized by hydrosilylation of the corresponding arylmenthyl olefin with commercially available silsesquioxane-type hydrosilane. We evaluated the applicability of the silsesquioxane-based compound to diastereoselective [2+2] photocycloaddition reaction. The newly synthesized silsesquioxane-based chiral menthol derivative 9 indicated similar diastereoselectivity to the corresponding p-methoxyphenyl menthol derivative.
