680580-85-2

Basic information

• Product Name: Cyclohexanol, 2-[1-(4-methoxyphenyl)-1-methylethyl]-5-methyl-, acetate, (1R,2S,5R)-
• CAS NO: 680580-85-2
• Molecular Formula: C19H28O3
• Molecular Weight: 304.43
• Mol File: 680580-85-2.mol

Chemical Properties

• CAS DataBase Reference: Cyclohexanol, 2-[1-(4-methoxyphenyl)-1-methylethyl]-5-methyl-, acetate, (1R,2S,5R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanol, 2-[1-(4-methoxyphenyl)-1-methylethyl]-5-methyl-, acetate, (1R,2S,5R)-(680580-85-2)
• EPA Substance Registry System: Cyclohexanol, 2-[1-(4-methoxyphenyl)-1-methylethyl]-5-methyl-, acetate, (1R,2S,5R)-(680580-85-2)

Safety Data

• Hazardous Substances Data: 680580-85-2(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 80868-36-6 (-)-8-[(p-methoxy)phenyl]menthol 

Downstream Products

• 1383941-67-0 C₂₉H₄₆O₃ 
• 1383941-68-1 C₂₇H₄₄O₂ 
• 1428424-13-8 (3aS,3bS,7aS,7bR)-(1R,2S,5R)-5-methyl-2-(2-(4-(octyloxy)phenyl)propan-2-yl)cyclohexyl 7-oxodecahydro-1H-cyclopenta[3,4]cyclobuta[1,2]benzene-3b-carboxylate 
• 1428424-07-0 (1S,6S)-(1R,2S,5R)-5-methyl-2-(2-(4-(octyloxy)phenyl)propan-2-yl)cyclohexyl 5-oxobicyclo[4.2.0]octane-1-carboxylate 
• 1428424-08-1 (1R,6R)-(1R,2S,5R)-5-methyl-2-(2-(4-(octyloxy)phenyl)propan-2-yl)cyclohexyl 5-oxobicyclo[4.2.0]octane-1-carboxylate 
• 1428424-06-9 (1R,2S,5R)-5-methyl-2-(2-(4-(octyloxy)phenyl)propan-2-yl)cyclohexyl 3-oxocyclohex-1-enecarboxylate 
• 1428424-05-8 (1R,2S,5R)-5-methyl-2-(2-(4-(octyloxy)phenyl)propan-2-yl)cyclohexanol 
• 680580-87-4 Acetic acid (1R,2S,5R)-2-(1-{4-[6-(tert-butyl-dimethyl-silanyloxy)-hexyloxy]-phenyl}-1-methyl-ethyl)-5-methyl-cyclohexyl ester 
• 680580-84-1 Acetic acid (1R,2S,5R)-2-{1-[4-(6-hydroxy-hexyloxy)-phenyl]-1-methyl-ethyl}-5-methyl-cyclohexyl ester 
• 680580-83-0 (-)-8-[(p-methoxy)phenyl]menthyl acetate 

Relevant articles and documents

Synthesis and evaluation of a chiral menthol functionalized silsesquioxane: Application to diastereoselective [2+2] photocycloaddition

A novel chiral menthol derivative supported on silsesquioxane was easily synthesized by hydrosilylation of the corresponding arylmenthyl olefin with commercially available silsesquioxane-type hydrosilane. We evaluated the applicability of the silsesquioxane-based compound to diastereoselective [2+2] photocycloaddition reaction. The newly synthesized silsesquioxane-based chiral menthol derivative 9 indicated similar diastereoselectivity to the corresponding p-methoxyphenyl menthol derivative.

Diastereoselective [2+2] photocycloaddition of chiral cyclic enones with olefins in aqueous media using surfactants

We conducted diastereodifferentiating [2+2] photocycloadditions of cyclo-hexenones modified with a chiral 8-(p-methoxy phenyl)menthyl auxiliary with olefins in water. Although the photoreaction didn't proceed at all in pure water owing to very low solubil

Diastereoselective [2+2] photocycloaddition of polymer-supported cyclic chiral enone with ethylene

The phenylmenthyl derivative, previously shown to be very effective chiral auxiliaries in the diastereoselective [2+2] photocycloaddition of cyclic enones with the simplest olefin, ethylene, was attached to poly(ethylene glycol)-grafted Wang resin. We the