138397-45-2Relevant academic research and scientific papers
New Routes Towards Halogeno Complexes of Gold by Halide Exchange from . Crystal and Molecular Structure of Triphenylmethylium Tetrachloroaurate(III),
Dell'Amico, Daniela Belli,Calderazzo, Fausto,Morvillo, Antonio,Pelizzi, Giancarlo,Robino, Pierluigi
, p. 3009 - 3016 (1991)
Anhydrous and AuI can be obtained by halide exchange from with RX (X = Br or I, R = H or alkyl).The addition of to CPh3Cl produces the ionic derivative whose crystal and molecular structure has been determined by X-ray diffraction.Crystal data: space group P21/c, a = 8.225(3), b = 14.671(6), c = 16.738(8) Angstroem, β = 97.85(2) deg and Z = 4.Other organic chlorides RCl (R = Pr, SiMe3 or But) react with with a partial reduction to the mixed-valence chloride .Addition of to anhydrous iron(III) chloride produced a mass-spectrometrically active mixed iron-gold species.
