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New Routes Towards Halogeno Complexes of Gold by Halide Exchange from . Crystal and Molecular Structure of Triphenylmethylium Tetrachloroaurate(III),

DOI: 10.1039/DT9910003009

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3009 - 3016 (1991)

Update date:2022-09-26

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Authors:

Dell'Amico, Daniela BelliDell'Amico, Daniela Belli

Calderazzo, FaustoCalderazzo, Fausto

Morvillo, AntonioMorvillo, Antonio

Pelizzi, GiancarloPelizzi, Giancarlo

Robino, PierluigiRobino, Pierluigi

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Article abstract of DOI:10.1039/DT9910003009

Anhydrous and AuI can be obtained by halide exchange from with RX (X = Br or I, R = H or alkyl).The addition of to CPh3Cl produces the ionic derivative whose crystal and molecular structure has been determined by X-ray diffraction.Crystal data: space group P21/c, a = 8.225(3), b = 14.671(6), c = 16.738(8) Angstroem, β = 97.85(2) deg and Z = 4.Other organic chlorides RCl (R = Pr, SiMe3 or But) react with with a partial reduction to the mixed-valence chloride .Addition of to anhydrous iron(III) chloride produced a mass-spectrometrically active mixed iron-gold species.

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Product name:triphenylmethylium tetrachloroaurate

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