New Routes Towards Halogeno Complexes of Gold by Halide Exchange from . Crystal and Molecular Structure of Triphenylmethylium Tetrachloroaurate(III),

DOI: 10.1039/DT9910003009

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3009 - 3016 (1991)

Update date:2022-09-26

Topics:

Authors:

Dell'Amico, Daniela Belli

Calderazzo, Fausto

Morvillo, Antonio

Pelizzi, Giancarlo

Robino, Pierluigi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9910003009

Anhydrous and AuI can be obtained by halide exchange from with RX (X = Br or I, R = H or alkyl).The addition of to CPh3Cl produces the ionic derivative whose crystal and molecular structure has been determined by X-ray diffraction.Crystal data: space group P2₁/c, a = 8.225(3), b = 14.671(6), c = 16.738(8) Angstroem, β = 97.85(2) deg and Z = 4.Other organic chlorides RCl (R = Pr, SiMe3 or Bu^t) react with with a partial reduction to the mixed-valence chloride .Addition of to anhydrous iron(III) chloride produced a mass-spectrometrically active mixed iron-gold species.

Full text of DOI:10.1039/DT9910003009

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:triphenylmethylium tetrachloroaurate

Cas No:138397-45-2

R&D Labs maybe for 138397-45-2

Innua Petrochem Ltd.

Contact:+1-284-4950244

Address:Box 3069, Road Town, Tortola, British Virgin Islands
Xuzhou Tianrun Chemical Co.,Ltd

website:http://www.tianrunchem.cn

Contact:86-516-83832636

Address:fuxing road
Tianjin Chemsyntech Chemical Co., Ltd

Contact:+86-22-60872258

Address:Haitai green industry base in Tianjin, K1,5-601
NANCHANG QINZHI SCI&TEC.CO.,LTD(expird)

Contact:+86-13687004106

Address:Hero South Road,Hero Zone,Nanchang,Jiangxi,China
Rayfull Holding Co., Ltd

Contact:+86-577-65618087-605

Address:Room 402, Unit 4 Xinhu Bldg. Waitan Ruian City, Zhejiang China.

Relevant to this article

Photodegradation of lipopolysaccharides and the inhibition of macrophage activation by anthraquinone-boronic acid hybrids

Doi:10.1039/c2cc33559j
(2012)
An efficient and one-pot synthesis of 1,2-dihydro-3H-naphtho[2,1-b]pyran-3-ones

Doi:10.3184/174751915X14360187398046
(2015)
Tandem one-pot construction of indoles via palladium and copper-catalyzed coupling reactions of the blaise reaction intermediate

Doi:10.1055/s-0031-1289753
(2012)
Palladium(II)-catalyzed oxidative C-H/C-H cross-coupling between two structurally similar azoles

Doi:10.1002/chem.201103813
(2012)
Doi:10.1021/jo01150a015
(1950)
Novel Inhibitors of Prolyl 4-Hydroxylase. 2. 5-Amide Substituted Pyridine-2-carboxylic Acids

Doi:10.1021/jm00083a002
(1992)

Article Doi