138404-01-0Relevant articles and documents
Structural Parallels Between the Cardiotonic Steroids and the Erythrophleum Alkaloids - I. Synthesis of Phenanthrenone Precursors to Novel Erythrophleum Alkaloid Analogues
Baker, Robert W.,Knox, John R.,Rogers, Dan H.
, p. 7951 - 7964 (1991)
(4aR*, 10R*, 10aR*)-10-Hydroxy-7-methoxy-3,4,4a,9,10,10a-hexahydrophenanthren-2(1H)-one (3) has been synthesised with the key step involving intramolecular electrophilic alkylation of the aromatic ring, via a Pummerer rear