32831-00-8

Basic information

• Product Name: 3-Hexanone, 1-chloro-
• Synonyms: 1-chloro-hexan-3-one;1-Chlor-hexan-3-on;3-Hexanone,1-chloro;1-chloro-3-hexanone
• CAS NO: 32831-00-8
• Molecular Formula: C6H11ClO
• Molecular Weight: 134.606
• Mol File: 32831-00-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Hexanone, 1-chloro-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Hexanone, 1-chloro-(32831-00-8)
• EPA Substance Registry System: 3-Hexanone, 1-chloro-(32831-00-8)

Safety Data

• Hazardous Substances Data: 32831-00-8(Hazardous Substances Data)

Upstream product

• 887144-97-0 Togni's reagent 
• 40122-38-1 1-propyl-1-cyclopropanol 

Downstream Products

• 32373-06-1 1-(benzyl-methyl-amino)-hexan-3-one 
• 130214-79-8 cis-3-ethyl-1-(2-hydroxyethyl)-2-<1-(phenylsulfonyl)-2-indolyl>-4-piperidone ethylene acetal 
• 130179-22-5 3-ethyl-2-<1-(phenylsulfonyl)-2-indolyl>-4-piperidone ethylene acetal 
• 130179-22-5 3-ethyl-2-<1-(phenylsulfonyl)-2-indolyl>-4-piperidone ethylene acetal 
• 130179-24-7 cis-3-ethyl-2-<1-(phenylsulfonyl)-2-indolyl>-4-piperidone 
• 130179-24-7 trans-3-ethyl-2-<1-(phenylsulfonyl)-2-indolyl>-4-piperidone 
• 130179-27-0 cis-3-ethyl-N-(hydroxyethyl)-2-<1-(phenylsulfonyl)-2-indolyl>-4-piperidone 
• 130179-20-3 3,3-(ethylenedioxy)-N-<<1-(phenylsulfonyl)-2-indolyl>methylene>hexylamine 
• 138404-07-6 Methyl (6R^*7S^*,8R^*)-6-Ethyl-8-(4'-Methoxyphenyl)-1,4-dioxaspiro<4.5>decane-7-carboxylate 
• 138404-07-6 (6R,7R,8S)-6-Ethyl-8-(4-methoxy-phenyl)-1,4-dioxa-spiro[4.5]decane-7-carboxylic acid methyl ester 
• 95518-06-2 2-(3-oxohexyl)-2-cyclohexen-1-one 
• 138404-01-0 2-Ethyl-1-hydroxy-6-(4'-methoxyphenyl)-3-oxocyclohexanecarboxylic Acid 
• 53472-34-7 2-(3-oxocyclohexyl)-1,3-cyclohexanedione 
• 35938-31-9 6-Methyl-2-<3-oxo-hexyl>-cyclohexanon 

Relevant articles and documents

Simple access to β-trifluoromethyl-substituted ketones via copper-catalyzed ring-opening trifluoromethylation of substituted cyclopropanols

Tertiary cyclopropanols react rapidly with Togni reagent in methanol at room temperature in the presence of catalytic amounts (3 mol%) of CuCl affording β-trifluoromethyl ketones in 65-73% isolated yields. Ring opening in 1,2-dialkylsubstituted cyclopropanols gives a mixture of isomeric β-trifluoromethyl ketones in about 50% combined yield.