138407-95-1Relevant academic research and scientific papers
Exploring the Reactivity of Alkenes Bearing Silicon and/or Tin in the Hydroxyl-Directed Hydrogenation. A Diastereoselective Synthesis of Heterobimetallic Compounds
Lautens, Mark,Zhang, C. H.,Goh, Betty Jane,Crudden, Cathleen M.,Johnson, Marc J. A.
, p. 6208 - 6222 (1994)
The hydroxyl-directed hydrogenation of (E)- and (Z)-γ-hydroxy vinylstannanes and silanes has been studied in the presence of (dppb)Rh(NBD)BF4 (1).Efficient routes to γ-hydroxy stannanes and silanes vave been developed.Diastereoselectivities from 60 to >50
