Exploring the Reactivity of Alkenes Bearing Silicon and/or Tin in the Hydroxyl-Directed Hydrogenation. A Diastereoselective Synthesis of Heterobimetallic Compounds

DOI: 10.1021/jo00100a023

Source and publish data:

Journal of Organic Chemistry p. 6208 - 6222 (1994)

Update date:2022-08-04

Topics: alkenes Diastereoselective Silicon

Authors:

Lautens, Mark

Zhang, C. H.

Goh, Betty Jane

Crudden, Cathleen M.

Johnson, Marc J. A.

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Article abstract of DOI:10.1021/jo00100a023

The hydroxyl-directed hydrogenation of (E)- and (Z)-γ-hydroxy vinylstannanes and silanes has been studied in the presence of (dppb)Rh(NBD)BF4 (1).Efficient routes to γ-hydroxy stannanes and silanes vave been developed.Diastereoselectivities from 60 to >50

Full text of DOI:10.1021/jo00100a023

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