Journal of Organic Chemistry p. 6208 - 6222 (1994)
Update date:2022-08-04
Topics: alkenes Diastereoselective Silicon
Lautens, Mark
Zhang, C. H.
Goh, Betty Jane
Crudden, Cathleen M.
Johnson, Marc J. A.
The hydroxyl-directed hydrogenation of (E)- and (Z)-γ-hydroxy vinylstannanes and silanes has been studied in the presence of (dppb)Rh(NBD)BF4 (1).Efficient routes to γ-hydroxy stannanes and silanes vave been developed.Diastereoselectivities from 60 to >50
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