138426-41-2Relevant academic research and scientific papers
Potassium t-butoxide or silver acetate induced ring enlargement of silacyclobutane into silacyclopentane. Application to the Synthesis of 1,4-Diol
Matsumoto, Kozo,Miura, Katsukiyo,Oshima, Koichiro,Utimoto, Kiitiro
, p. 6383 - 6386 (1991)
Treatment of 1-(1-iodoalkyl)-1-silacyclobutanes with t-BuOK or AgOAc provided 2-alkyl-1-silacyclopentanes which were easily converted into 1,4-diols by oxidative cleavage of carbon-silicon bonds.
Nucleophile-induced ring enlargement of 1-(1-iodoalkyl)silacyclobutane and 1-(1,2-epoxyalkyl)silacyclobutane into silacyclopentane. Application to the synthesis of 1,4-diol, 4-alken-1-ol, and 1,4,5-triol
Matsumoto,Takeyama,Miura,Oshima,Utimoto
, p. 250 - 261 (2007/10/02)
Two methods for ring enlargement of silacyclobutane into silacyclopentane have been described. (1) Treatment of 1-(1-iodoalkyl)silacyclobutane with t-BuOK or AgOAc provided 2-alkyl-1-silacyclopentanes which were easily converted into 1,4-diols by oxidativ
