Potassium t-butoxide or silver acetate induced ring enlargement of silacyclobutane into silacyclopentane. Application to the Synthesis of 1,4-Diol

DOI: 10.1016/0040-4039(91)80175-6

Source and publish data:

Tetrahedron Letters p. 6383 - 6386 (1991)

Update date:2022-08-02

Topics:

Authors:

Matsumoto, Kozo

Miura, Katsukiyo

Oshima, Koichiro

Utimoto, Kiitiro

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Article abstract of DOI:10.1016/0040-4039(91)80175-6

Treatment of 1-(1-iodoalkyl)-1-silacyclobutanes with t-BuOK or AgOAc provided 2-alkyl-1-silacyclopentanes which were easily converted into 1,4-diols by oxidative cleavage of carbon-silicon bonds.

Full text of DOI:10.1016/0040-4039(91)80175-6

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