1384281-07-5Relevant academic research and scientific papers
Regioselective electrophilic addition vs epoxidation of mCPBA towards anti-Bredt olefin of fulleroid
Ikuma, Naohiko,Sumioka, Satoko,Asahara, Haruyasu,Oshima, Takumi
experimental part, p. 3581 - 3584 (2012/09/08)
The mCPBA oxidation of methano-bridged [5,6] open fulleroid 1 anomalously resulted in the selective electrophilic addition at the bridgehead anti-Bredt double bond rather than the usual epoxidation. The mechanistic preference for the unprecedented stepwis
