1384451-30-2

Upstream product

• 52199-35-6 tetrakis-5,10,15,20-(o-aminophenyl)porphyrin 
• 13446-03-2 manganese(II) bromide 
• 52199-35-6 cis-α,α,α,α-atropisomer 5,10,15,20-tetrakis(2-aminophenyl)porphyrin 

Downstream Products

• 857288-34-7 C₉₂H₆₀ClMnN₈O₈ 
• 1384270-13-6 C₉₂H₆₂ClMnN₈O₉ 
• 1384270-13-6 (NH₂C₆H₄)(C₆H₄NHCOC₁₀H₅OCH₃)2(C₆H₄NHCOC₂₀H₁₀(OCH₃)2COOH)C₂₀H₈N₄MnCl 

Relevant academic research and scientific papers

H2O2/NaHCO3-mediated enantioselective epoxidation of olefins in NTf2-based ionic liquids and under ultrasound

The bicarbonate-activated peroxide (BAP) system has been shown to constitute an excellent and versatile combination for the epoxidation of olefins. Herein, we demonstrate that the benign H2O 2/NaHCO3 oxidative combination can be used for the enantioselective epoxidation of olefins using a chiral manganese porphyrin as a catalyst. This unprecedented result was made possible by the use of an ionic liquid with ultrasound, which leads to the activation of Mn-porphyrin catalysis.