857288-34-7Relevant academic research and scientific papers
H2O2/NaHCO3-mediated enantioselective epoxidation of olefins in NTf2-based ionic liquids and under ultrasound
Chatel, Gregory,Goux-Henry, Catherine,Mirabaud, Anais,Rossi, Thomas,Kardos, Nathalie,Andrioletti, Bruno,Draye, Micheline
, p. 127 - 132 (2012/08/13)
The bicarbonate-activated peroxide (BAP) system has been shown to constitute an excellent and versatile combination for the epoxidation of olefins. Herein, we demonstrate that the benign H2O 2/NaHCO3 oxidative combination can be used for the enantioselective epoxidation of olefins using a chiral manganese porphyrin as a catalyst. This unprecedented result was made possible by the use of an ionic liquid with ultrasound, which leads to the activation of Mn-porphyrin catalysis.
