1384465-95-5Relevant academic research and scientific papers
Salicylaldehyde Hydrazones: Buttressing of Outer-Sphere Hydrogen-Bonding and Copper Extraction Properties
Roach, Benjamin D.,Lin, Tai,Bauer, Heiko,Forgan, Ross S.,Parsons, Simon,Rogers, David M.,White, Fraser J.,Tasker, Peter A.
, p. 556 - 565 (2017)
Salicylaldehyde hydrazones are weaker copper extractants than their oxime derivatives, which are used in hydrometallurgical processes to recover ～20% of the world's copper. Their strength, based on the extraction equilibrium constant Ke, can be increased by nearly three orders of magnitude by incorporating electron-withdrawing or hydrogen-bond acceptor groups (X) ortho to the phenolic OH group of the salicylaldehyde unit. Density functional theory calculations suggest that the effects of the 3-X substituents arise from a combination of their influence on the acidity of the phenol in the pH-dependent equilibrium, Cu2++2Lorg→[Cu(L-H)2]org+2H+, and on their ability to 'buttress' interligand hydrogen bonding by interacting with the hydrazone N-H donor group. X-ray crystal structure determination and computed structures indicate that in both the solid state and the gas phase, coordinated hydrazone groups are less planar than coordinated oximes and this has an adverse effect on intramolecular hydrogen-bond formation to the neighbouring phenolate oxygen atoms.
Synthesis and characterization of new extractants for Cu(II)
Zhang, Xing,Hui, Jianbin
, p. 4229 - 4231 (2013/07/25)
New extractants for Cu2+ ions in raw ore powders or waste water (fluid) were successfully synthesized recently in good yields. Their structures and purity were confirmed by 1H NMR and IR.
