1384480-73-2Relevant academic research and scientific papers
A new two dimensional copper (II) coordination complex with sulphonamide: Synthesis, crystal structure and DNA binding study
Devi, W. Bembee,Singh, R.K. Bhubon,Jasinski,Golen
, p. 163 - 167 (2012)
A novel copper (II) complex, [Cu(HL)2] (where, HL = 3-(4-(sulphonamine)phenylimino)-1-phenylbut-1-en-1-ol) has been synthesized and characterized by IR, UV-vis, magnetic susceptibility measurement and single crystal X-ray crystallographic studies. The crystal data confirm the square planarity of the prepared complex having an orthorhombic space group Pca2 (1). Molecular packing of the complex is stabilized by N - H...O hydrogen bonding and weak N - H...O, C - H...Cg π-ring intermolecular interactions, hence forming a two dimensional supramolecular network structure. CT-DNA binding studies have been carried out by monitoring electronic absorption titrations, luminescence titrations, a DNA melting, cyclic voltametry and viscosity measurement studies. An intercalative mode of DNA binding is suggested for the prepared copper (II) complex.
