1384546-00-2

Upstream product

• 115375-24-1 (E)-3-(4-(allyloxy)-3-methoxyphenyl)acrylic acid 
• 183625-03-8 methyl (1S,3R,4R,5S,2'S,3'S)-1,3-dihydroxy-4,5-[2,3-dimethoxybutane-2,3-di(yloxy)]cyclohexane-1-carboxylate 
• 183474-88-6 methyl (1S,4S,5R)-1-hydroxy-4,5-<(2S,3S)-2,3-dimethoxybutan-2,3-dioxy>-3-oxo-cyclohexan-1-carboxylate 
• 176798-26-8 (2S,3S,4aR,6S,8R,8aR)-6,8-Dihydroxy-2,3-dimethoxy-2,3-dimethyl-octahydro-benzo[1,4]dioxine-6-carboxylic acid methyl ester 
• 77-95-2 D-(-)-quinic acid 
• 1135-24-6 (E)-3-(4-hydroxy-3-methoxyphenyl)acrylic acid 
• 850786-96-8 (E)-3-methoxy-4-allyloxycinnamoyl chloride 
• 1384545-88-3 C₂₇H₃₆O₁₁ 

Downstream Products

• 1384546-04-6 methyl 3-feruloyl-muco-quinate 
• 1384546-15-9 3-O-feruloyl-muco-quinic acid 

Relevant academic research and scientific papers

First diastereoselective synthesis of methyl caffeoyl- and feruloyl-muco-quinates

We report on a diastereoselective synthesis of six derivatives of caffeoyl- and feruloyl-muco-quinic acids. All the muco-quinic acid derivatives were obtained in excellent yield in five steps starting from quinic acid, caffeic acid and ferulic acid. Allyl ether protection of trans-hydroxy cinnamic acids was here introduced to chlorogenic acids synthesis. We show that muco-quinic acid derivatives, which are formally diastereoisomers of chlorogenic acids, can be readily distinguished by their tandem mass spectra. The Royal Society of Chemistry 2012.