138469-75-7Relevant academic research and scientific papers
Acidic-functionalized ionic liquid as an efficient, green, and metal-free catalyst for benzylation of sulfur, nitrogen, and carbon nucleophiles to benzylic alcohols
Chu, Xue-Qiang,Jiang, Ran,Fang, Yi,Gu, Zheng-Yang,Meng, Hua,Wang, Shun-Yi,Ji, Shun-Jun
supporting information, p. 1166 - 1174 (2013/02/25)
A series of HSO4- functionalized ILs was synthesized and used as efficient, green, and metal-free catalysts for benzylation. Notably, the catalytic system has wide substrate scopes and the ionic liquid catalysts were applied to investigate three different types of nucleophiles to give the desired benzylation products with moderate to excellent yields.
THE USE OF o-MITROARYLACETONITRILES IN THE MITSUNOBU REACTION: MECHANISTIC IMPLICATIONS AND SYNTHETIC APPLICATIONS
Macor, John E.,Wehner, Jennifer M.
, p. 349 - 365 (2007/10/02)
o-Nitroarylacetonitriles (1) have been used as carbon acid participants in the Mitsunobu reaction to yield 2-(o-nitroaryl)-2-alkylacetonitriles (2).Reductive cyclization of 2 afforded 3-alkylindoles (3) in moderate yield.The use of o-nitroarylacetonitrile
THE USE OF o-NITROARYLACETONITRILES AS CARBON ACID PARTICIPANTS IN THE MITSUNOBU REACTION
Macor, John E.,Wehner, Jennifer M.
, p. 7195 - 7198 (2007/10/02)
The use of o-nitroarylacetonitriles as carbon acids in the Mitsunobu reaction is discussed as a method of carbon-carbon bond formation.This reaction represents a rare example of a carbon acid participating in a Mitsunobu reaction.
