1384835-07-7

Upstream product

• 1384834-98-3 C₁₇H₂₄O₄S 
• 1384835-01-1 (1S,5S)-5-((S)-1-(4-methoxyphenoxy)propan-2-yl)-2-methylcyclohex-2-enol 
• 1384835-03-3 2,2,2-trichloro-N-((1R,5R)-5-((S)-1-(4-methoxyphenoxy)propan-2-yl)-2-methylcyclohex-2-enyl)acetamide 
• 1384835-04-4 methyl (1R,5R)-5-((S)-1-(4-methoxyphenoxy)propan-2-yl)-2-methylcyclohex-2-enylcarbamate 
• 1384835-05-5 methyl (hydroxymethyl) ((1R,5R)-((S)-1-(4-methoxyphenoxy)propan-2-yl)-2-methylcyclohex-2-enyl)carbamate 
• 1384835-06-6 methyl ((2-hydroxy-5-oxocyclopent-1-en-1-yl)methyl)-((1R,5R)-5-((S)-1-(4-methoxyphenoxy)propan-2-yl)-2-methylcyclohex-2-en-1-yl)carbamate 
• 75-36-5 acetyl chloride 
• 150-76-5 4-methoxy-phenol 
• 552289-36-8 (1S,5S)-5-((S)-2-Hydroxy-1-methyl-ethyl)-2-methyl-cyclohex-2-enol 

Downstream Products

• 1384835-10-2 (2aR,2a⁽¹⁾R,4R,5aS,5bS,8R,8aS)-methyl 5b-acetoxy-8-hydroxy-4-((S)-1-(4-methoxyphenoxy)propan-2-yl)-2a⁽¹⁾-methyldecahydrocyclopenta[1,4]cyclobuta[1,2,3-cd]indole-1-carboxylate 
• 1384835-00-0 C₂₈H₃₉NO₉S 
• 1384835-09-9 (2aR,2a⁽¹⁾R,6aS,8R,9aR)methyl 8-((S)-1-(4-methoxyphenoxy)propan-2-yl)-2a⁽¹⁾-methyl-3,6-dioxododecahydro-1H-cyclohepta[cd]indole-1-carboxylate 
• 1384835-08-8 (2aR,2a⁽¹⁾R,4R,5aS,5bS,8aR)methyl 5b-acetoxy-4-((S)-1-(4-methoxyphenoxy)propan-2-yl)-2a⁽¹⁾-methyl-8-oxodecahydrocyclopenta[1,4]cyclobuta[1,2,3-cd]indole-1-carboxylate 

Relevant academic research and scientific papers

Tackling reactivity and selectivity within a strained architecture: Construction of the [6-6-5-7] tetracyclic core of calyciphylline alkaloids

A stereochemically controlled route to the enantiopure [6-6-5-7] tetracyclic core of Calyciphylline A class alkaloids was established, which involves Overman rearrangement, [2 + 2] photochemical cycloaddition, Grob fragmentation, C-N bond-forming nucleophilic displacement, and ring strain-directed hydrogenation as strategic steps.