1384897-25-9Relevant academic research and scientific papers
New Pyridinium Ylide Dyes for Dye Sensitized Solar Cell Applications
Li, Ting-Yu,Su, Chaochin,Akula, Suri Babu,Sun, Wei-Gang,Chien, Hung-Ming,Li, Wen-Ren
, p. 3386 - 3389 (2016)
Novel organic pyridinium ylide sensitizers (NO109-111) consisting of various anchoring groups were synthesized and characterized for applications in dye sensitized solar cells. Compared with the pyridine-N-oxide dye (NO108), the ylide sensitizers with strong electron-withdrawing acceptors exhibited dominant ultraviolet absorption properties and efficient binding abilities to the TiO2 surface. Among these dyes, the pyridinium ylide NO111 sensitized solar cell showed the highest efficiency (5.15%), which was improved to 7.41% by employing coadsorbent chenodeoxycholic acid.
Making benzotrithiophene derivatives dopant-free for perovskite solar cells: Step-saving installation of π-spacers by a direct C-H arylation strategy
Peng, Yi-Kai,Lee, Kun-Mu,Ting, Chang-Chieh,Hsu, Ming-Wei,Liu, Ching-Yuan
, p. 24765 - 24770 (2019/11/14)
Previously, benzotrithiophene (BTT)-based hole-transporting materials (HTMs) had to be doped with three chemical agents for high-efficiency perovskite solar cells (PSC). This work describes significant progress by which the first dopant-free BTT core-based HTM (YKP03) with EDOT spacers was readily accessed by step-saving direct C-H arylation. PSCs with dopant-free YKP03 showed promising efficiencies of up to 16.15% with potential long-term storage stability.
Perovskite hole transport material based on triptycene mother nucleus and preparation method thereof
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, (2018/11/03)
The present invention discloses a perovskite hole transport material based on a triptycene mother nucleus and a preparation method thereof. The material is 2,6,14-tri(50-(N,N-bi(4-methoxyphenyl)aminophenol-4-yl)-3,4-ethylenedioxythiophene-2-yl)-triptycene. The preparation method has the advantages of mild synthesis conditions, simple steps, cheap and easily obtained synthetic raw materials, and low synthesis costs. The prepared material has a good thermal stability, solubility and film forming property. An ultraviolet-visible light absorption spectrum indicates the hole transport material based on the triptycene mother nucleus has a large conjugate structure, has a more suitable HOMO level (-5.08 eV) than that of a mainstream hole transport material Spiro-MeOTAD, and provides a strong driving force for hole transporting. The carrier mobility of the material measured by a space charge limiting current method is 8x10cm.Vs. The perovskite hole transport material has potential.
Embedding an electron donor or acceptor into naphtho[2,1-b:3,4-b′] dithiophene based organic sensitizers for dye-sensitized solar cells
Feng, Quanyou,Jia, Xiaowei,Zhou, Gang,Wang, Zhong-Sheng
supporting information, p. 7445 - 7447 (2013/09/23)
An electron donor and acceptor, respectively, is embedded into naphtho[2,1-b:3,4-b′]dithiophene based organic sensitizers to tune their optoelectronic properties. The DSSC based on FNE52 containing an auxiliary electron acceptor displays a maximum power conversion efficiency of 8.2% and good long-term stability.
