1384974-54-2Relevant academic research and scientific papers
Catalytic, atom-economical radical arylation of epoxides
Gansaeuer, Andreas,Behlendorf, Maike,Von Laufenberg, Daniel,Fleckhaus, Andre,Kube, Christian,Sadasivam, Dhandapani V.,Flowers II, Robert A.
supporting information; experimental part, p. 4739 - 4742 (2012/06/30)
A slow electron waltz: Catalysis in single-electron steps with radicals as intermediates is essential for an atom-economical arylation of epoxides with a proton-coupled electron transfer as a key step. Stabilization of the catalyst is essential for low catalyst loading, as demonstrated by reaction-progress kinetic analysis, cyclic voltammetry, and calculations. Copyright
