1385022-69-4

Upstream product

• 109-09-1 2-chloropyridine 
• 1310403-97-4 2-(4-ethoxy-3-methylphenyl)-1,3,2-dioxaborolane 
• 79636-93-4 4-bromo-1-ethoxy-2-methylbenzene 
• 109-04-6 2-bromo-pyridine 

Relevant academic research and scientific papers

Superstable palladium(0) complex as an air-and thermostable catalyst for Suzuki coupling reactions

An unprecedentedly thermo-and air-stable Pd0 complex from readily available electron-poor trifluoromethylated phosphine was serendipitously discovered. As detailed and comparative DFT calculations indicate, the stability of the complex is associated with unusually strong ligand-ligand noncovalent interactions. The unique stability and the presence of hydrophobic structural elements of the complex offer several practical advantages, which were exploited in catalytic Suzuki-Miyaura coupling reactions.

A NEW PALLADIUM CATALYST, METHOD FOR ITS PREPARATION AND ITS USE

The invention relates to palladium(0)-tetrakis{tri-[3,5-bis(trifluoromethyl)- phenylj-phosphine} complex of formula (I), as well as to its preparation and use. This compound is outstandingly stable, and can be used as catalyst with excellent results.