138536-07-9Relevant academic research and scientific papers
1,3-Dipolar Cycloaddition Between Ethyl Trifluoroacetoacetate and N-(Benzylidene)methylamine N-Oxide
Begue, Jean-Pierre,Bonnet-Delpon, Daniele,Lequeux, Thierry
, p. 2888 - 2889 (1991)
The 1,3-dipolar cycloaddition between ethyl trifluoroacetoacetate and N-(benzylidene)methylamine N-oxide, performed in boiling toluene, leads regio- and stereo-selectively to an isoxazolidine, while the corresponding ethyl acetoacetate is found to be unreactive under the same conditions.On the other hand, α-trifluoromethylstyrene behaves as α-methylstyrene and affords two diastereoisomeric trifluoromethyl-substituted cycloadducts.
