138536-52-4Relevant academic research and scientific papers
Utilization of Me3SiSnBu3 in organic synthesis I. Generation of stannyl anion from Me3SiSnBu3 and R4NX
Mori, Miwako,Kaneta, Naotake,Isono, Naohiro,Shibasaki, Masakatsu
, p. 255 - 260 (2007/10/02)
A metal free stannyl anion generated from Me3SiSBu3 and R4NX in DMF reacted with an aryl halide bearing carbonyl group to produce an aryl anion via the so-called halogen-metal exchange process, which reacted with a carbonyl group to afford a cyclized product in good yield.
Reaction of Metal Free Bu3Sn- Generated from Bu3SnSiMe3-R4NX with an Aryl or Vinyl Halide
Mori, Miwako,Kaneta, Naotake,Isono, Naoshiro,Shibasaki, Masakatsu
, p. 6139 - 6142 (2007/10/02)
Metal free stannyl anion generated from Bu3SnSiMe3 and R4NX in DMF reacted with an aryl or vinyl halide to produce the aryl or vinyl anion via so-called halogen-metal exchange process, which reacted with internal carbonyl group to afford cyclized product in good yield. Key Words: Bu3NSnSiMe3, Bu3Sn(1-)*R4N(1+), Metal free stannyl anion, Cyclization, Aryl or Vinyl anion
