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ETHYL 5-(4-METHOXYPHENYL)-2-THIOPHENECARBOXYLATE, commonly known as Tetramethrin, is a synthetic insecticide belonging to the pyrethroid class of chemicals. It is a powerful neurotoxin that effectively targets and disrupts the nervous system of insects, resulting in paralysis and death. ETHYL 5-(4-METHOXYPHENYL)-2-THIOPHENECARBOXYLATE is widely used in household and agricultural pest control products due to its rapid knockdown of insects and relatively low mammalian toxicity.

13858-71-4

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13858-71-4 Usage

Uses

Used in Household Pest Control:
ETHYL 5-(4-METHOXYPHENYL)-2-THIOPHENECARBOXYLATE is used as an insecticide in household pest control products for its effectiveness in rapidly eliminating a wide range of insects, providing quick relief from infestations.
Used in Agricultural Pest Control:
In the agricultural industry, ETHYL 5-(4-METHOXYPHENYL)-2-THIOPHENECARBOXYLATE is used as a crop protectant to control various insect pests that can damage crops and reduce yields. Its broad-spectrum action helps maintain crop health and productivity.
Used in Mosquito Control:
ETHYL 5-(4-METHOXYPHENYL)-2-THIOPHENECARBOXYLATE is used as an active ingredient in mosquito control products, such as mosquito coils and aerosol sprays, to prevent the breeding and spread of mosquitoes, which can transmit diseases.
Used in Pet Flea Control:
In the pet care industry, ETHYL 5-(4-METHOXYPHENYL)-2-THIOPHENECARBOXYLATE is used in flea collars and other treatments to protect pets from flea infestations, ensuring their comfort and health.
However, it is important to note that prolonged or excessive exposure to Tetramethrin can be harmful to humans, causing skin and respiratory irritation, headaches, and dizziness. Therefore, proper safety precautions should be taken when using products containing this chemical to minimize potential health risks.

Check Digit Verification of cas no

The CAS Registry Mumber 13858-71-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,8,5 and 8 respectively; the second part has 2 digits, 7 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 13858-71:
(7*1)+(6*3)+(5*8)+(4*5)+(3*8)+(2*7)+(1*1)=124
124 % 10 = 4
So 13858-71-4 is a valid CAS Registry Number.
InChI:InChI=1/C14H14O3S/c1-3-17-14(15)13-9-8-12(18-13)10-4-6-11(16-2)7-5-10/h4-9H,3H2,1-2H3

13858-71-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name ethyl 5-(4-methoxyphenyl)thiophene-2-carboxylate

1.2 Other means of identification

Product number -
Other names 2-Aethoxycarbonyl-5-p-methoxyphenyl-thiophen

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13858-71-4 SDS

13858-71-4Relevant academic research and scientific papers

Preparation of Functionalized Diorganomagnesium Reagents in Toluene via Bromine or Iodine/Magnesium-Exchange Reactions

Desaintjean, Alexandre,Danton, Fanny,Knochel, Paul

supporting information, p. 4461 - 4476 (2021/08/13)

A wide range of polyfunctionalized di(hetero)aryl- and dialkenyl-magnesium reagents are prepared in toluene within 10 to 120 minutes between 78 C and 25 C via an I/Mg- or Br/Mg-exchange reaction using reagents of the general formula R2Mg (R = sBu, Mes). Highly sensitive functional groups, such as triazene or nitro, are tolerated in these exchange reactions, enabling the synthesis of various functionalized (hetero)arene and alkene derivatives after quenching with several electrophiles including allyl bromides, acyl chlorides, aldehydes, ketones, and aryl iodides.

Programmed Synthesis of Tetra-Aryl Thiophenes with Stepwise, Ester-Controlled Regioselectivity

Messina, Cynthia,Ottenwaelder, Xavier,Forgione, Pat

supporting information, p. 7348 - 7352 (2021/10/01)

Herein, we report a modular synthetic route to access tetra-arylated thiophene compounds with four different substituents with programmed chemical control provided by an ester activating/directing group. This method enables the functionalization of indivi

Base catalyzed reaction of ethyl thioglycolate with β-aryl-β-(methylthio) acroleins: A general method for the synthesis of 2-carbethoxy-5-substituted/4,5-annulated thiophenes in high overall yields

Byre Gowda,Pradeepa Kumara,Ramesh,Sadashiva,Junjappa

supporting information, p. 928 - 931 (2016/02/05)

(Methylthio) acroleins 1a-m were shown to be stable unlike their counterpart the chloroacroleins and their efficacy as 1,3-dielectrophilic properties have now been examined successfully in this work. They are shown to react with ethyl thioglycolate in the

Highly functionalized biaryls via Suzuki-Miyaura cross-coupling catalyzed by Pd@MOF under batch and continuous flow regimes

Pascanu, Vlad,Hansen, Peter R.,Bermejo G?3mez, Antonio,Ayats, Carles,Platero-Prats, Ana E.,Johansson, Magnus J.,Peric??s, Miquel ??.,Mart??n-Matute, Bel??n

, p. 123 - 130 (2015/02/19)

A diverse set of more than 40 highly functionalized biaryls was synthesized successfully through the Suzuki-Miyaura cross-coupling reaction catalyzed by Pd nanoparticles supported in a functionalized mesoporous MOF (8 wt% Pd@MIL-101(Cr)-NH2). This could be achieved under some of the mildest conditions reported to date and a strong control over the leaching of metallic species could be maintained, despite the presence of diverse functional groups and/or several heteroatoms. Some of the targeted molecules are important intermediates in the synthesis of pharmaceuticals and we clearly exemplify the versatility of this catalytic system, which affords better yields than currently existing commercial procedures. Most importantly, Pd@MIL-101-NH2 was packed in a micro-flow reactor, which represents the first report of metallic nanoparticles supported on MOFs employed in flow chemistry for catalytic applications. A small library of 11 isolated compounds was created in a continuous experiment without replacing the catalyst, demonstrating the potential of the catalyst for large-scale applications.

Novel acyl hydrazino thiophene derivatives, process for preparing them, their use as medicinal products, pharmaceutical compositions and novel use

-

Page/Page column 16, (2010/02/12)

The invention concerns novel compounds of formula (I), process for making, pharmaceutical compositions and methods of treating diseases associated with abnormal physiological behavior in the secretion and/or the activity of cysteine proteases especially c

Microwave assisted synthesis of 5-arylthiophene-2-carboxylates

Jagath Reddy,Latha,Sailaja,Pallavi,Srinivasa Rao

, p. 411 - 414 (2007/10/03)

A simple and rapid method for the synthesis of 5-Aryl-thiophene-2- carboxylates 3 has been developed by the condensation of β-chlorovinyl aldehydes 1 with mercaptoacetic acid esters 2 under microwave irradiation conditions.

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