1385808-90-1

Basic information

• Product Name: 3-[6-O-(2-azido)acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl]prop-1-ene
• Synonyms: 3-[6-O-(2-azido)acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl]prop-1-ene
• CAS NO: 1385808-90-1
• Molecular Weight: 557.646
• Mol File: 1385808-90-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-[6-O-(2-azido)acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl]prop-1-ene(CAS DataBase Reference)
• NIST Chemistry Reference: 3-[6-O-(2-azido)acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl]prop-1-ene(1385808-90-1)
• EPA Substance Registry System: 3-[6-O-(2-azido)acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl]prop-1-ene(1385808-90-1)

Safety Data

• Hazardous Substances Data: 1385808-90-1(Hazardous Substances Data)

Upstream product

• 82614-11-7 [(2R,3R,4R,5S,6R)-3,4,5-tris(benzyloxy)-6-(prop-2-en-1-yl)oxan-2-yl]methanol 
• 88154-14-7 methyl 2,3,4-tri-O-benzyl-6-O-chloroacetyl-α-D-glucopyranoside 
• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 
• 762-72-1 allyl-trimethyl-silane 

Downstream Products

• 1385808-92-3 3-{2,3,4-tri-O-benzyl-6-O-{4-[(5-dimethylaminonaphthalene-1-sulfonylamino)methyl]-1H-1,2,3-triazol-1-yl}acetyl-α-D-glucopyranosyl}prop-1-ene 

Relevant articles and documents

Synthesis of triazole-linked fluorescent saccharides and glycosyl amino esters

Synthesis of fluorescent carbohydrates and glycopeptides has been emerging as an attractive research field because of various biological roles of carbohydrates and glycoproteins. Fluorescent glycosides and C-glycosides were synthesized by copper(I)-catalyzed Huisgen reaction between 6-O-(2-azidoacetyl) glycopyranosides and alkyne-functionalized fluorophores. For the fluorescent disaccharides as well as glycosyl amino acids derivatives, glycosylation of azido-functionalized thioglycosides, followed by click reaction with corresponding fluorophores is preferred than the inversed procedure (click reaction before the glycosylation). Fluorophores like dansyl, NBD, or rhodamine have been successfully introduced on the sugar ring. All the newly synthesized fluorescent glycosides and glycoconjugates showed similar photophysical properties to the native fluorophores, with a higher quantum yield for the dansyl derivatives. Georg Thieme Verlag Stuttgart · New York.