138587-96-9

Upstream product

• 2043-61-0 cyclohexanecarbaldehyde 
• 75-77-4 chloro-trimethyl-silane 
• 4352-44-7 1-cyclohexylprop-2-en-1-ol 
• 123159-55-7 <2-(trimethylsilyl)ethyl>tris(2-methylphenyl)phosphonium iodide 

Downstream Products

• 76436-98-1 (Z)-1-cyclohexyl-1-(trimethylsilyloxy)-1-propene 
• 1446696-17-8 (E)-2-(3-cyclohexylallyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 1446696-18-9 (Z)-pinacolato (3-cyclohexyl-2-propen-1-yl)boronate 
• 138587-75-4 syn-3-tert-butyl-5--4,5-dihydroisoxazole 
• 138587-75-4 anti-3-tert-butyl-5--4,5-dihydroisoxazole 

Relevant academic research and scientific papers

Stereoselective Dehydroxyboration of Allylic Alcohols to Access (E)-Allylboronates by a Combination of C-OH Cleavage and Boron Transfer under Iron Catalysis

Iron-catalyzed direct SN2′ dehydroxyboration of allylic alcohols has been developed to access (E)-stereoselective allylboronates. Allylic alcohols with diverse structures and functional groups, especially derived from natural products, underwent smooth transformation. The six-membered ring transition state formed by allylic alcohols and iron-boron intermediate was indicated to be the key component involved in transfer of the boron group, activation of the C-OH bond, and control of the stereoselectivity.

TRIS(2-METHYLPHENYL)PHOSPHORANE, A MODIFIED SEYFERTH-WITTIG REAGENT FOR THE STEREOSELECTIVE SYNTHESES OF Z-ALLYLTRIMETHYLSILANES

The Wittig reactions between title β-silylphosphorus ylide and aliphatic aldehydes give selectively Z-allyltrimethylsilanes with minimal formation of vinylation products.