138608-61-4

Upstream product

• 368446-57-5 (3aS,6S,7aS)-6-(tert-Butyl-dimethyl-silanyloxy)-2,2-dimethyl-tetrahydro-benzo[1,3]dioxol-4-one 
• 273402-73-6 (2S,3S,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-2,3-dihydroxy-cyclohexanone 
• 199613-48-4 5-tert-butyl-dimethylsilyloxy-(5S)-2-cyclohexenone 
• 155551-04-5 (3aS,7aS)-2,2-dimethyl-7,7a-dihydrobenzo[d][1,3]dioxol-4-(3aH)-one 
• 591-51-5 phenyllithium 
• 34244-66-1 cis-(2R,3S)-2,3-dihydroxy-1-phenylcyclohexa-4,6-diene 
• 77-76-9 2,2-dimethoxy-propane 

Downstream Products

• 921202-21-3 (1S,2R)-3-((3aR,7aS)-2,2-Dimethyl-3a,7a-dihydro-benzo[1,3]dioxol-4-yl)-cyclohexa-3,5-diene-1,2-diol 

Relevant academic research and scientific papers

Chemical synthesis of optically active cis-cyclohexa-3,5-diene-1,2-diols and their 5-2H-derivatives

A variety of optically active 3-substituted cis-cyclohexane-3,5-dien-1,2-diol acetonides were readily prepared from chiral 5-(tert-butyldimethylsilyloxy)-2-cyclohexenone through a seven-step reaction in good overall yield. The synthesis also allowed prepa

Dioxygenase-catalysed dihydroxylation of arene cis-dihydrodiols and acetonide derivatives: A new approach to the synthesis of enantiopure tetraoxygenated bioproducts from arenes

cis-Dihydrodiols of anthracene and benz[a]anthracene, and acetonide derivatives of the cis-dihydrodiols of benzene, fluorobenzene, biphenyl and phenanthrene have been identified as substrates for dioxygenase enzymes, yielding the corresponding enantiopure