138613-42-0

Basic information

• Product Name: 2-Propenoic acid, 2-methyl-3-(3,4,5-trimethoxyphenyl)-, methyl ester, (E)-
• CAS NO: 138613-42-0
• Molecular Formula: C14H18O5
• Molecular Weight: 266.294
• Mol File: 138613-42-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 2-methyl-3-(3,4,5-trimethoxyphenyl)-, methyl ester, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 2-methyl-3-(3,4,5-trimethoxyphenyl)-, methyl ester, (E)-(138613-42-0)
• EPA Substance Registry System: 2-Propenoic acid, 2-methyl-3-(3,4,5-trimethoxyphenyl)-, methyl ester, (E)-(138613-42-0)

Safety Data

• Hazardous Substances Data: 138613-42-0(Hazardous Substances Data)

Upstream product

• 157373-92-7 (+/-)-methyl 2-[hydroxy(3,4,5-trimethoxyphenyl)methyl]prop-2-enoate 
• 86-81-7 3,4,5-trimethoxy-benzaldehyde 
• 67-56-1 methanol 
• 121189-89-7 (E)-2-methyl-3-(3,4,5-trimethoxyphenyl)propenoic acid 

Downstream Products

• 121189-89-7 (E)-2-methyl-3-(3,4,5-trimethoxyphenyl)propenoic acid 
• 138613-39-5 (2RS,3SR)-2,3-dimethyl-1,4-bis(3,4,5-trimethoxyphenyl)butan-1-one 
• 138613-39-5 (2RS,3RS)-2,3-dimethyl-1,4-bis(3,4,5-trimethoxyphenyl)butan-1-one 
• 72730-21-3 (2R,3S)-2,3-Dimethyl-1,4-bis-(3,4,5-trimethoxy-phenyl)-butan-1-ol 
• 72730-21-3 (2R,3R)-2,3-Dimethyl-1,4-bis-(3,4,5-trimethoxy-phenyl)-butan-1-ol 
• 138613-41-9 3-methyl-1,4-bis(3,4,5-trimethoxyphenyl)butan-1-one 
• 138613-45-3 2-methyl-3-(3,4,5-trimethoxyphenyl)propyl p-toluenosulfonate 
• 138613-44-2 2-methyl-3-(3,4,5-trimethoxyphenyl)propan-1-ol 
• 14335-63-8 (1α,2β,3α)-6,7,8-trimethoxy-2,3-dimethyl-1-(3,4,5-trimethoxyphenyl)-1,2,3,4-tetrahydronaphthalene 
• 14335-63-8 (1α,2β,3β)-6,7,8-trimethoxy-2,3-dimethyl-1-(3,4,5-trimethoxyphenyl)-1,2,3,4-tetrahydronaphthalene 
• 138613-43-1 methyl 2-methyl-3-(3,4,5-trimethoxyphenyl)propanoate 

Relevant articles and documents

A facile one-pot stereoselective synthesis of trisubstituted (E)-2-methylalk-2-enoic acids from unactivated Baylis-Hillman adducts and a simple access to some important insect pheromones

An efficient one-pot stereoselective synthesis of trisubstituted (E)-2-methylalk-2-enoic acids has been accomplished by treatment of unactivated Baylis-Hillman adducts, 3-hydroxy-2-methylenealkanoates, with Al-NiCl2·6H2O in methanol at room temperature followed by hydrolysis. The method has been applied to the synthesis of three important insect pheromones, (4S,2E)-2,4-dimethyl-2-hexenoic acid, (+)-(S)-manicone and (+)-(S)-normanicone.