138638-64-9

Basic information

• Product Name: Methyl 4,6-O-benzylidene-3-deoxy-3-phenylselenyl-α-D-altropyranoside
• Synonyms: Methyl 4,6-O-benzylidene-3-deoxy-3-phenylselenyl-α-D-altropyranoside
• CAS NO: 138638-64-9
• Molecular Weight: 421.352
• Mol File: 138638-64-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Methyl 4,6-O-benzylidene-3-deoxy-3-phenylselenyl-α-D-altropyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 4,6-O-benzylidene-3-deoxy-3-phenylselenyl-α-D-altropyranoside(138638-64-9)
• EPA Substance Registry System: Methyl 4,6-O-benzylidene-3-deoxy-3-phenylselenyl-α-D-altropyranoside(138638-64-9)

Safety Data

• Hazardous Substances Data: 138638-64-9(Hazardous Substances Data)

Upstream product

• 1666-13-3 diphenyl diselenide 
• 3150-15-0 methyl 2,3-anhydro-4,6-O-benzilidene-α-D-mannopyranoside 
• 23974-72-3 sodium phenylselenide 

Downstream Products

• 138638-75-2 Methyl 2-O-allyl-4,6-O-benzylidene-3-deoxy-3-phenylselenyl-α-D-altropyranoside 
• 74524-02-0 methyl 4,6-O-(phenylmethylene)-3-deoxy-α-D-erythro-hexopyranoside-2-ulose 
• 138638-78-5 Methyl 4,6-O-benzylidene-3-C-<1,1-dimethyl-2-propenyl>-α-D-ribo-hexopyranosid-2-ulose 
• 138638-85-4 Methyl 4,6-O-benzylidene-3-C-<1,1-dimethyl-2-propenyl>-α-D-arabino-hexopyranosid-2-ulose 
• 138638-77-4 Methyl 4,6-O-benzylidene-3-C-<1-methyl-2-propenyl>-α-D-ribo-hexopyranosid-2-ulose 
• 138638-84-3 Methyl 4,6-O-benzylidene-3-C-<1-methyl-2-propenyl>-α-D-arabino-hexopyranosid-2-ulose 
• 138638-90-1 Methyl 4,6-O-benzylidene-3-C-<(1S)-1-methyl-3-hydroxypropyl>-α-D-glucopyranoside 
• 138638-89-8 Methyl 4,6-O-benzylidene-3-C-<(1R)-1-methyl-3-hydroxypropyl>-α-D-glucopyranoside 
• 138638-80-9 Methyl 2-O-allyl-4,6-O-benzylidene-3-deoxy-α-D-erythro-hex-2-enopyranoside 
• 138750-14-8 Methyl 4,6-O-benzylidene-3-C-<(1S)-1-methyl-3-hydroxypropyl>-α-D-arabino-hexopyranosid-2-ulose 
• 138638-88-7 Methyl 4,6-O-benzylidene-3-C-<(1R)-1-methyl-3-hydroxypropyl>-α-D-arabino-hexopyranosid-2-ulose 
• 138750-15-9 (2R,4aR,6S,6aR,10S,10aS,10bS)-6-Methoxy-10-methyl-2-phenyl-perhydro-8H-pyrano<3',2':4,5>pyrano<3,2-d>-1,3-dioxin 
• 138638-91-2 (2R,4aR,6S,6aR,10R,10aS,10bS)-6-Methoxy-10-methyl-2-phenyl-perhydro-8H-pyrano<3',2':4,5>pyrano<3,2-d>-1,3-dioxin 
• 138638-83-2 (2R,4aR,6S,8aS)-6-Methoxy-7-(3-methyl-but-2-enyloxy)-2-phenyl-4,4a,6,8a-tetrahydro-pyrano[3,2-d][1,3]dioxine 

Relevant articles and documents

Ulose formation by selenoxide elimination

Ring opening of methyl 2,3-anhydro-(R)-4,6-O-benzylidene-α-D- mannopyranoside with phenyl selenide gives (R)-4,6-O-benzylidene-3-Se- phenyl-3-seleno-α-D-altropyranoside (2). Oxidation of (2) with H2O2 followed by thermolysis gives methyl (R)-4,6-O-benzylidene-3-deoxy-α-D- erythrohexopyranosid-2-ulose via syn-elimination and ketoenol tautomerization.