138694-28-7

Upstream product

• 138694-12-9 Bis(2,2,2-trifluoroethyl) 3-(methoxycarbonyl)-3-methylprop-2-enylphosphonate 
• 138694-27-6 (2R,3R,4E,6S,7R,8S,10S,11R)-<(tert-Butyldimethylsilyl)oxy>-11-(2,5-dimethoxy-3-nitrophenyl)-8-hydroxy-N,7,8,11-tetramethoxy-N,2,4,6,10-pentamethyl-4-undecenal 
• 1026820-20-1 C₆H₉Cl₂O₃P 
• 138694-20-9 Ethyl (2E,4S,5R,6E)-5-Methoxy-2,4-dimethyl-7-phenyl-2,6-heptadienoate 
• 1026339-86-5 (2R,3R,4E,6S,7R,10S,11R)-3-(tert-Butyldimethylsilyloxy)-11-(2,5-dimethoxy-3-nitrophenyl)-N,7,11-trimethoxy-N,2,4,6,10-pentamethyl-8-oxo-9-<(2-thioxo-3-thiazolidinyl)carbonyl>-4-undecenamide 
• 138721-95-6 (2R,3R,4E,6S,7R,10S,11R)-3-(tert-Butyldimethylsilyloxy)-11-(2,5-dimethoxy-3-nitrophenyl)-8-hydroxy-N,7,11-trimethoxy-N,2,4,6,10-pentamethyl-9-<(2-thioxo-3-thiazolidinyl)carbonyl>-4-undecenamide 
• 138694-25-4 (2R,3R,4E,6S,7R,10S,11R)-3-(tert-Butyldimethylsilyloxy)-11-(2,5-dimethoxy-3-nitrophenyl)-8-oxo-N,7,11-trimethoxy-N,2,4,6,10-pentamethyl-4-undecenamide 
• 138721-96-7 (2R,3R,4E,6S,7R,8S,10S,11R)-3-(tert-Butyldimethylsilyloxy)-11-(2,5-dimethoxy-3-nitrophenyl)-N,7,8,11-tetramethoxy-N,2,4,6,10-pentamethyl-4-undecenamide 
• 138694-26-5 (2R,3R,4E,6S,7R,8S,10S,11R)-3-(tert-Butyldimethylsilyloxy)-11-(2,5-dimethoxy-3-nitrophenyl)-8-hydroxy-N,7,11-trimethoxy-N,2,4,6,10-pentamethyl-4-undecenamide 
• 138694-21-0 (4R,5S)-3-<(2R,3R,4E,6S,7R,8E)-3-Hydroxy-7-methoxy-2,4,6-trimethyl-9-phenyl-4,8-nonadienoyl>-4-methyl-5-phenyl-2-oxazolidinone 
• 138694-23-2 (2R,3R,4E,6S,7R,8E)-3-<(tert-Butyldimethylsilyl)oxy>-N,7-dimethoxy-9-phenyl-N,2,4,6-tetramethyl-4,8-nonadienamide 
• 138694-16-3 (4R,5S)-3-<(2R,3R,4E)-3-Hydroxy-2-methyl-5-phenyl-4-pentenoyl>-4-methyl-5-phenyl-2-oxazolidinone 
• 138694-22-1 (2R,3R,4E,6S,7R,8E)-N,7-Dimethoxy-3-hydroxy-9-phenyl-N,2,4,6-tetramethyl-4,8-nonadienamide 
• 138694-11-8 (2R,3R,4E,6S,7R)-3-<(tert-Butyldimethylsilyl)oxy>-7-formyl-N,7-dimethoxy-N,2,4,6-tetramethyl-4-heptenamide 

Downstream Products

• 130740-44-2 macbecin I 
• 123083-98-7 (2E,4Z,6S,7R,8E,10S,11R,12S,14S,15R)-15-(3-Amino-2,5-dimethoxyphenyl)-7-(tert-butyldimethylsiloxy)-11,12,15-trimethoxy-2,6,8,10,14-pentamethyl-2,4,8-pentadecatrienoic acid 
• 73341-72-7 macbecin I 
• 138694-29-8 Methyl (2E,4Z,6S,7R,8E,10S,11R,12S,14S,15R)-15-(3-amino-2,5-dimethoxyphenyl)-7-(tert-butyldimethylsiloxy)-11,12,15-trimethoxy-2,6,8,10,14-pentamethyl-2,4,8-pentadecatrienoate 

Relevant academic research and scientific papers

An improved synthesis of the (E,Z)-dienoate precursor of (+)-damavaricin D via a vinylogous Horner-Wadsworth-Emmons reaction

An improved synthesis of the C(1)-C(5) (E,Z)-dienoate segment of (+)- damavaricin D precursor 3 was accomplished using the unsaturated phosphonate reagent 9 in a (Z)-selective vinylogous Horner-Wadsworth-Emmons reaction.