13871-93-7Relevant academic research and scientific papers
Palladium-catalyzed silylation of alcohols with hexamethyldisilane
Shirakawa, Eiji,Hironaka, Koji,Otsuka, Hidehito,Hayashi, Tamio
, p. 3927 - 3929 (2006)
The combination of hexamethyldisilane and a catalytic amount of [PdCl(η3-C3H5)]2-PPh 3 was found to be effective for the trimethylsilylation of alcohols, where both of the two trimethylsilyl groups of hexamethyldisilane were transferred to alcohols without coproduction of any stoichiometric amount of byproduct but H2. The Royal Society of Chemistry 2006.
Why Are Silyl Ethers Conformationally Different from Alkyl Ethers? Chair-Chair Conformational Equilibria in Silyloxycyclohexanes and Their Dependence on the Substituents on Silicon. The Wider Roles of Eclipsing, of 1,3-Repulsive Steric Interactions, and o
Marzabadi, Cecilia H.,Anderson, J. Edgar,Gonzalez-Outeirino, Jorge,Gaffney, Piers R. J.,White, Christopher G. H.,Tocher, Derek A.,Todaro, Louis J.
, p. 15163 - 15173 (2007/10/03)
An NMR study of the diaxial/diequatorial chair equilibrium in a range of silylated derivatives of trans-1,4- and trans-1,2-dihydroxycyclohexane is reported and discussed with a view to explaining unusually large populations of chair conformations with axi
A FACILE SYNTHESIS OF 2,3,4,6-TETRA-O-BENZYL-D-GLUCOPYRANOSYLIDENE ACETALS USING TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE CATALYST
Yoshimura, Juji,Horito, Shigeomi,Hashimoto, Hironobu
, p. 375 - 376 (2007/10/02)
The application of acetalization of aldehydes and ketones by alkoxysilanes in the presence of trimethylsilyl trifluoromethanesulfonate catalyst to lactones and di-O-trimethylsilyl-α-diols gave readily the corresponding spiro ortho esters.
