1387578-80-4Relevant articles and documents
Visible-light and thermal driven double hydrophosphination of terminal alkynes using a commercially available iron compound
Ackley, Brandon J.,Pagano, Justin K.,Waterman, Rory
, p. 2774 - 2776 (2018)
A commercially available iron compound, [CpFe(CO)2]2 (1) (Cp = η5-C5H5), is an efficient catalyst for the double hydrophosphination of terminal aryl alkynes with diphenylphosphine under visible light irradiation or thermal conditions with a reduction of reaction times of up to two orders of magnitude for some substrates over literature reports. The 1,2-bis(diphenylphosphino)ethane products generated in these reactions are readily isolated in high yields.
Regioselective double hydrophosphination of terminal arylacetylenes catalyzed by an iron complex
Kamitani, Masahiro,Itazaki, Masumi,Tamiya, Chihiro,Nakazawa, Hiroshi
supporting information; experimental part, p. 11932 - 11935 (2012/09/08)
The first catalytic double hydrophosphination of alkynes was achieved by reaction with diarylphosphines in the presence of an iron catalyst. The double hydrophosphination proceeded regioselectively and effectively for various secondary arylphosphines and