138760-67-5Relevant articles and documents
Reaction of pyranoid and furanoid aldonolactones with chloromethyltrimethylsilane-derived reagents
Glanzer,Csuk
, p. 79 - 92 (2007/10/02)
Reaction of pyranoid and furanoid aldonolactones with trimethylsilylmethyl-lithium provides a convenient route to carbon-chain-elongated methyl ketones. Reaction of the lactones with chloro(trimethylsilyl)methyl-lithium gives the corresponding chloromethylketones. Reaction of pyranoid and furanoid aldonolactones with trimethylsilylmethyl-lithium provides a convenient route to carbon-chain-elongated methyl ketones. Reaction of the lactones with chloro(trimethylsilyl)methyl-lithium gives the corresponding chloromethylketones.