1387605-75-5

Upstream product

• 917087-42-4 1-phenylethynylcyclopropyl methyl ketone 
• 593-56-6 N-methoxylamine hydrochloride 
• 1202394-47-5 1-(1-(phenylethynyl)cyclopropyl)ethanol 
• 67-62-9 O-Methylhydroxylamin 
• 6746-94-7 Cyclopropylacetylene 
• 591-50-4 iodobenzene 
• 21777-85-5 cyclopropylphenylethyne 
• 1009319-37-2 1-(2-phenylethynyl)cyclopropanecarbaldehyde 

Downstream Products

• 1387605-99-3 3-(2-(benzyloxy)ethyl)-1-methoxy-2-methyl-5-phenyl-1H-pyrrole 
• 1646540-93-3 2-methoxy-1-methyl-3-phenyl-5,6-dihydrocyclopenta[c]pyrrol-4(2H)-one 

Relevant academic research and scientific papers

Gold(I)-catalyzed regio- and stereoselective 1,3-dipolar cycloaddition reactions of 1-(1-Alkynyl)cyclopropyl oximes with nitrones: A modular entry to highly substituted pyrrolo[3,4-d][1,2]oxazepines

An efficient approach for the synthesis of highly substituted pyrrolo[3,4-d][1,2]oxazepines has been achieved by gold(I)-catalyzed 1,3-dipolar cycloaddition reactions of 1-(1-alkynyl)cyclopropyl oximes with nitrones in good to excellent yields as a single diastereomer. A complete chirality transfer was observed in this transformation. Copyright

Pd(II)-Catalyzed Tandem Heterocyclization of 1-(1-Alkynyl)cyclopropyl Oxime Derivatives for the Synthesis of Functionalized Pyrroles

An efficient approach for the synthesis of highly functionalized pyrroles has been developed by a Pd(TFA)2-catalyzed tandem heterocyclization of 1-(1-alkynyl)cyclopropyl oxime derivatives under mild conditions. The reaction first proceeded via an intramolecular nucleophilic attack followed by a ring-opening process and then intermolecular nucleophilic attack as well as protonation to afford the desired products in moderate to excellent yields.

Catalyst-dependent divergent synthesis of pyrroles from 3-alkynyl imine derivatives: A noncarbonylative and carbonylative approach

A novel Ru0- and RhI-catalyzed noncarbonylative and carbonylative cycloisomerization of readily available 3-alkynyl imine derivatives has been developed to provide 3,4-fused or nonfused pyrrole derivatives efficiently in moderate to

Highly substituted pyrroles by a gold(I)-catalyzed tandem reaction of 1-(1-alkynyl)cyclopropyl oxime ethers with nucleophiles

A gold(I)-catalyzed tandem reaction of 1-(1-alkynyl) cyclopropyl oxime ethers with nucleophiles under mild conditions has been developed, which provides a facile access to highly substituted pyrroles in moderate to excellent yields. Georg Thieme Verlag St