138769-95-6Relevant articles and documents
Palladium-Catalyzed Coupling of Terminal Alkynes to the Free cis-Diol Metabolite Produced from the Oxidation of Bromobenzene by Pseudomonas putida: Synthesis of New Homochiral 3-Alkynyl cis-Cyclohexa-3,5-diene-1,2-diols
Hudlicky, Tomas,Boros, Eric E.
, p. 217 - 220 (2007/10/02)
The free cis-diol metabolite (1) produced from the oxidation of bromobenzene by Pseudomonas putida underwent Pd(0)-catalyzed coupling with trimethylsilyl acetylene, phenylacetylene and 1-hexyne providing the novel homochiral (1S,2R)-3-alkynyl cis-cyclohex