138770-95-3Relevant academic research and scientific papers
On the Preparation and Rearrangement of Some Vinylic Sulphoxides
Cass, Quezia B.,Jaxa-Chamiec, Albert A.,Kunec, Ellen K.,Sammes, Peter G.
, p. 2683 - 2686 (2007/10/02)
The condensation of methyl benzenesulphinylacetate 1 with a series of aldehydes has been explored using different catalysts.With zinc chloride, the enolate of 1 produces the conjugated ester directly.A base-catalysed rearrangement of these conjugated este
Preparation and Rearrangement of Some Conjugated Phenylsulphinylacetate Derivatives
Cass, Quezia B.,Jaxa-Chamiec, Albert A.,Sammes, Peter G.
, p. 1248 - 1250 (2007/10/02)
The direct condensation of saturated or unsaturated aldehydes with methyl phenylsulphinylacetate can be effected with the products undergoing base-catalysed rearrangements, those from saturated aldehydes yielding γ-hydroxy-αβ-unsaturated esters, whilst crotonaldehyde gives rise to methyl 6-phenylsulphinylhexa-2,4-dienoate.
