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138785-37-2

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138785-37-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 138785-37-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,8,7,8 and 5 respectively; the second part has 2 digits, 3 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 138785-37:
(8*1)+(7*3)+(6*8)+(5*7)+(4*8)+(3*5)+(2*3)+(1*7)=172
172 % 10 = 2
So 138785-37-2 is a valid CAS Registry Number.

138785-37-2Relevant articles and documents

Studies related to the carbohydrate sectors of esperamicin and calicheamicin: Definition of the stability limits of the esperamicin domain and fashioning of a glycosyl donor from the calicheamicin domain

Halcomb, Randall L.,Boyer, Serge H.,Wittman, Mark D.,Olson, Steven H.,Denhart, Derek J.,Liu, Kevin K. C.,Danishefsky, Samuel J.

, p. 5720 - 5749 (2007/10/02)

The core trisaccharide regions of esperamicin and the aryltetrasaccharide region of calicheamicin have been synthesized. The minimum protection modalities necessary to stabilize structures against rearrangement to an isomeric azafuranose series were ascertained (see compounds 12 and 65). Deprotection of the 2-(trimethylsilyl)-ethoxycarbonyl carbamate from 65 led to azafuranose 14 characterized as methyl glycoside 15. Using this insight, it was possible to fashion, for the first time, a pre-glycosyl donor (see compound 128) corresponding to the complete arylsaccharide sector of calicheamicin γ1I at the oxidation level of the domain. Among the key assembly strategies were the conversion of α-thiophenylpseudoglycals to allal derivatives (see 44 → 45); the interfacing of epoxide-mediated glycosylation with iodoglycosylation (see 30 → 47 → 48); the synthesis of hydroxylamine glycosides via inflate displacement (see 61 + 91 → 101); and a new route to p-hydroxybenzonitriles (see formation of 86).

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