1388002-17-2Relevant academic research and scientific papers
Nickel-catalyzed regio- and stereoselective reductive coupling between methylenecyclopropanes, aldehydes, and triethylborane with retention of the cyclopropane ring
Ogata, Kenichi,Shimada, Daisuke,Fukuzawa, Shin-Ichi
supporting information; experimental part, p. 6142 - 6146 (2012/06/18)
Running rings: The first regio- and stereoselective reductive coupling between methylenecyclopropanes, aldehydes, and triethylborane with retention of the cyclopropane ring was achieved using a nickel-phosphine catalyst (see scheme). The reductive coupling reaction constructed a stereo-defined cyclopropane ring with formation of a quaternary stereogenic carbon center. Copyright
