1388136-05-7Relevant academic research and scientific papers
Synthesis of15N-labeled heterocyclesviathe cleavage of C-N bonds of anilines and glycine-15N
He, Jiwen,Zhang, Xingguo,He, Qiuqin,Guo, Hao,Fan, Renhua
supporting information, p. 5442 - 5445 (2021/06/09)
A nitrogen replacement process that directly incorporates the15N atom of glycine-15N into anilines was reported. The process involves a Csp2-N bond cleavage of anilines driven by dearomatization and a Csp3-N bond cleavage of glycine-15N driven by aromatization. A variety of15N-labeled aromatic heterocycles can be preparedviathis process.
Visible-Light-Mediated [2+2+1] Carbocyclization Reactions of 1,7-Enynes with Bromofluoroacetate to Form Fused Monofluorinated Cyclopenta[ c]quinolin-4-ones
Li, Yongqiang,Liu, Yuxiu,Qu, Yi,Song, Hongjian,Wang, Qingmin,Xu, Wentao,Zhang, Jingjing
, p. 5379 - 5389 (2020/05/19)
Herein, we describe a new protocol for photoinduced radical [2+2+1] carbocyclization reactions of 1,7-enynes with bromofluoroacetate. These reactions, which proceed via a cascade involving fluoroalkylation, 6-exo-dig and 5-endo-trig cyclizations, H-transf
