138825-36-2Relevant academic research and scientific papers
A Zirconium Catalysed Synthesis of 1,4-Dimagnesium Reagents.
Lewis, Dorian P.,Muller, Philippe M.,Whitby, Richard J.,Jones, Raymond V. H.
, p. 6797 - 6800 (2007/10/02)
The zirconium catalysed addition of diethylmagnesium to a variety of unactivated alkenes affords either the simple carbometallation product, or 1,4-dimagnesium reagents depending on the conditions and substrate.The products can be successfully functionalised with a variety of electrophiles.Key Words: Zirconium; Grignard; Carbometallation; 1,4-Dimagnesium; Catalysis.
