138833-12-2Relevant academic research and scientific papers
Asymmetric Synthesis of Oxygen- and Nitrogen-Substituted Difluoromethylene Products
Bravo, Pierfrancesco,Pregnolato, Massimo,Resnati, Giuseppe
, p. 2726 - 2731 (2007/10/02)
1,1-Difluoroalkyl sulfinylmethyl ketones 3 are synthesized in enantiomerically pure form through acylation of (+)-(R)-methyl p-tolyl sulfoxide (1) with α,α-difluorocarboxylates 2.These ketones have been reduced with complete diastereoselection to give the
A NEW ENTRY TO HOMOCHIRAL DIFLUORINATED COMPOUNDS
Bravo, Pierfrancesco,Pregnolato, Massimo,Resnati, Giuseppe
, p. 1105 - 1106 (2007/10/02)
Some homochiral compounds containing a difluoromethylene unit along with oxygen and nitrogen functionalities have been obtained starting from α,α-difluorocarboxylic esters and (+)-(R)-methyl p-tolyl sulfoxide.
