13886-07-2

Upstream product

• 17497-53-9 1-iodo-1-cyclohexene 
• 116858-81-2 trimethylpyrrolidinylcarbonylstannane 
• 116883-46-6 tributylpyrrolidinylcarbonylstannane 
• 116858-84-5 triphenylpyrrolidinylcarbonylstannane 
• 1125-99-1 1-(1-Cyclohexen-1-yl)pyrrolidine 
• 75-62-7 Bromotrichloromethane 
• 123-75-1 pyrrolidine 
• 36278-22-5 1-cyclohexenoyl chloride 
• 636-82-8 cyclohexene-1-carboxylic acid 

Downstream Products

• 1187052-05-6 (2-(3-methylbut-2-enyl)cyclohex-1-enyl)(pyrrolidin-1-yl)methanone 
• 1110635-72-7 (2-(1,2-diphenylvinyl)-cyclohex-1-enyl)pyrrolidin-1-ylmethanone 

Relevant academic research and scientific papers

Direct allylation of aromatic and α,β-unsaturated carboxamides under ruthenium catalysis

The ruthenium-catalyzed oxidative allylation of aromatic and α,β-unsaturated carboxamides with allylic carbonates is described. These transformations proceed readily with complete linear γ-selectivity of substituted allylic carbonates. the Partner Organisations 2014.

Organic Synthesis with Carbon Monoxide: The Synthesis of Carbamoylstannanes and Aromatic Carbamoylation

The lithium salts of secondary amines were carbonylated and the carbamoyl-lithium species (1) produced quenched with ketones, alkyl halides and trialkyltin chlorides.The latter gave tributyl-, triphenyl- and trimethyl-carbamoylstannanes (2) in good yield.These were found to undergo palladium-catalysed cross coupling with aryl, alkenyl, and hetaryl halides (I, Br) to give amides (4), (5), and (6) respectively, in fair to excellent yield, the trimethyl series being the reagents of choice.

The Intermediacy of Trichloromethyl Anions in the Reaction of Enamines with Bromotrichloromethane

Reaction of N-(cyclohex-1-enyl)pyrrolidine with bromotrichloromethane in dimethyl sulphoxide generates trichloromethyl anions with have been trapped by addition to iminium cationsw or converted into chloroform in the presence of a hydrogen ion source.