138921-72-9Relevant academic research and scientific papers
Highly Diastereoselective Michael Addition Reactions of Lithium Enolates to Ethyl 3-Trifluoromethylacrylate
Yamazaki, Takashi,Haga, Jiro,Kitazume, Tomoya,Nakamura, Shinichiro
, p. 2171 - 2174 (1991)
Michael addition reactions of lithium enolates derived from ketones, esters, and amides to ethyl 3-trifluoromethylacrylate were found to proceed smoothly in moderate to excellent chemical yields as well as with a high degree of diastereoselectivity at the
Stereoselective Synthesis of Trifluoromethylated Compounds with Controlled Adjacent Tertiary Carbons by Michael Addition to (E)-3-(Trifluoromethyl)acrylates
Shinohara, Noriyasu,Haga, Jiro,Yamazaki, Takashi,Kitazume, Tomoya,Nakamura, Shinichiro
, p. 4363 - 4374 (2007/10/02)
Michael addition reaction of various lithium enolates to ethyl (E)-3-(trifluoromethyl)acrylate (E)-1 was found to be one of the most effective routes to construct materials not only with a CF3 group but also readily distinguishable multiple functionalitie
