13894-26-3

Basic information

• Product Name: (E)-1--2-tosylethylene
• Synonyms: (E)-1--2-tosylethylene
• CAS NO: 13894-26-3
• Molecular Weight: 281.419
• Mol File: 13894-26-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (E)-1--2-tosylethylene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1--2-tosylethylene(13894-26-3)
• EPA Substance Registry System: (E)-1--2-tosylethylene(13894-26-3)

Safety Data

• Hazardous Substances Data: 13894-26-3(Hazardous Substances Data)

Upstream product

• 13894-21-8 ethynyl p-tolyl sulfone 
• 108-18-9 diisopropylamine 
• 66823-38-9 1-ethynylsulfanyl-4-methyl-benzene 
• 7087-68-5 N-ethyl-N,N-diisopropylamine 
• 98-59-9 p-toluenesulfonyl chloride 
• 3541-14-8 phenyl toluene-4-thiosulfonate 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 
• 4526-53-8 cis-1,2-bis-(p-tolylthio)ethylene 

Relevant articles and documents

Electrochemical Coupling of Arylsulfonyl Hydrazides and Tertiary Amines for the Synthesis of β-Amidovinyl Sulfones

The reaction of arylsulfonyl hydrazides with tertiary amines provided β-amidovinyl sulfones in good yields under mild electrochemical conditions. The reactions were carried out using an acid, in a solution of nBu4NBF4 in dimethyl sulfoxide in undivided cells with graphite-platinum electrodes under a constant current. The arylsulfonyl hydrazides and tertiary amines were activated via a radical process by electrochemical oxidation and reacted to give the desired β-amidovinyl sulfones.

Visible light-mediated dehydrogenative β-arylsulfonylation of tertiary aliphatic amines with arylsulfonyl chlorides

The novel synthesis of β-arylsulfonyl enamines has been achieved by visible light-mediated dehydrogenative arylsulfonylation of tertiary aliphatic amines with arylsulfonyl chlorides in moderate yield. This journal is