138943-64-3Relevant academic research and scientific papers
Reaction of unstabilized iodonium ylides with organoboranes
Ochiai, Masahito,Tuchimoto, Yoshimi,Higashiura, Nobuyuki
, p. 1505 - 1508 (2004)
Exposure of monocarbonyl iodonium ylides, generated by the ester exchange of (Z)-(2-acetoxyvinyl)-λ3-iodanes with EtOLi, to organoboranes results in a 1,2-shift of a carbon ligand from boron to the ylide carbons, which probably generates hitherto uncharacterized α-boryl ketones.
