139061-24-8

Basic information

• Product Name: Ethanone, 1-[(3aR,6aS)-3a,4,5,6a-tetrahydro-2-methylfuro[2,3-b]furan-3-yl]-,
• Synonyms: Ethanone, 1-[(3aR,6aS)-3a,4,5,6a-tetrahydro-2-methylfuro[2,3-b]furan-3-yl]-,
• CAS NO: 139061-24-8
• Molecular Formula: C9H12O3
• Molecular Weight: 168.18978
• Product Categories: ACETYLGROUP
• Mol File: 139061-24-8.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Ethanone, 1-[(3aR,6aS)-3a,4,5,6a-tetrahydro-2-methylfuro[2,3-b]furan-3-yl]-,(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[(3aR,6aS)-3a,4,5,6a-tetrahydro-2-methylfuro[2,3-b]furan-3-yl]-,(139061-24-8)
• EPA Substance Registry System: Ethanone, 1-[(3aR,6aS)-3a,4,5,6a-tetrahydro-2-methylfuro[2,3-b]furan-3-yl]-,(139061-24-8)

Safety Data

• Hazardous Substances Data: 139061-24-8(Hazardous Substances Data)

Upstream product

• 1191-99-7 2,3-dihydro-2H-furan 
• 123-54-6 acetylacetone 

Relevant articles and documents

Tetrabutylammonium peroxydisulfate in organic synthesis; IX: A convenient approach to the synthesis of fused acetal derivatives by tetrabutylammonium peroxydisulfate-mediated oxidative cycloaddition of 1,3-dicarbonyl compounds to cyclic enol ethers

A number of fused acetal derivatives were prepared in 82-90% yield by tetrabutylammonium peroxydisulfate-mediated oxidative cycloaddition of 1,3-diketones or 1,3-diketoesters to cyclic enol ethers in the presence of a base such as potassium acetate in acetonitrile.

Synthesis of fused acetal derivatives by manganic acetate promoted additions to endocyclic enol ethers

Reaction of manganic acetate in acetic acid with β-diketones and β-ketoesters leads to generation of intermediates, which add efficiently to endocyclic unsaturated enol ethers to afford fused acetals.

Synthesis Of Oxygen Spirocycles By Manganic Acetate Promoted Additions To Exocyclic Enol Ether Derivatives

Oxidative addition, promoted by manganic acetate, of β-dicarbonyl compounds to enol lactones and related enol derivatives having an exocyclic double bond affords spirocyclic products, and addition to endocyclic enol ethers gives fused acetals and ketals.