139077-41-1

Upstream product

• 139077-40-0 1-(2-Benzyloxy-6-[1,3]dioxan-2-yl-4-methoxy-phenyl)-4,5-dimethoxy-naphthalene-2-carboxylic acid methyl ester 

Downstream Products

• 36209-87-7 (-)-ancistrocladinine 
• 134276-88-3 (+)-(S)-3-benzyloxy-2-(4,5-dimethoxy-2-methyl-2-naphthyl)-5-methoxybenzaldehyde 
• 139077-42-2 (E)-(-)-(S)-1-<3-benzyloxy-2-(4,5-dimethoxy-2-methyl-1-naphthyl)-5-methoxyphenyl>-2-nitropropene 
• 134276-91-8 (-)-(S,1S)-N-<2-<3-hydroxy-2-(4,5-dimethoxy-2-methyl-1-naphthyl)-5-methoxyphenyl>-1-methylethyl>acetamide 
• 134276-91-8 (-)-(S,1R)-N-<2-<3-hydroxy-2-(4,5-dimethoxy-2-methyl-1-naphthyl)-5-methoxyphenyl>-1-methylethyl>acetamide 
• 36209-87-7 (-)-(S,3R)-6-hydroxy-5-(4,5-dimethoxy-2-methyl-1-naphthyl)-8-methoxy-3,4-dihydro-1,3-dimethylisoquinoline 
• 134276-89-4 (S)-2-[3-Benzyloxy-2-(4,5-dimethoxy-2-methyl-naphthalen-1-yl)-5-methoxy-phenyl]-1-methyl-ethylamine 
• 134276-89-4 (R)-2-[3-Benzyloxy-2-(4,5-dimethoxy-2-methyl-naphthalen-1-yl)-5-methoxy-phenyl]-1-methyl-ethylamine 
• 134276-92-9 Acetic acid 3-((R)-2-acetylamino-propyl)-2-(4,5-dimethoxy-2-methyl-naphthalen-1-yl)-5-methoxy-phenyl ester 
• 134276-92-9 Acetic acid 3-((S)-2-acetylamino-propyl)-2-(4,5-dimethoxy-2-methyl-naphthalen-1-yl)-5-methoxy-phenyl ester 
• 134276-90-7 (-)-(S,1S)-N-<2-<3-benzyloxy-2-(4,5-dimethoxy-2-methyl-1-naphthyl)-5-methoxyphenyl>-1-methylethyl>acetamide 
• 134276-90-7 (-)-(S,1R)-N-<2-<3-benzyloxy-2-(4,5-dimethoxy-2-methyl-1-naphthyl)-5-methoxyphenyl>-1-methylethyl>acetamide 

Relevant academic research and scientific papers

Synthetic Approaches to the Alkaloids of the Ancistrocladaceae. Part 3. The Total Synthesis of (-)-Ancistrocladinine: Control of the Diastereoisomer Excess in the Synthesis of Axially Chiral Biaryls.

The total synthesis of the naphthylisoquinoline alkaloid (-)-ancistrocladinine is described.The key step was the construction of the disymmetric bi