36209-87-7Relevant academic research and scientific papers
Synthetic Approaches to the Alkaloids of the Ancistrocladaceae. Part 3. The Total Synthesis of (-)-Ancistrocladinine: Control of the Diastereoisomer Excess in the Synthesis of Axially Chiral Biaryls.
Rizzacasa, Mark A.,Sargent, Melvyn V.
, p. 2773 - 2782 (2007/10/02)
The total synthesis of the naphthylisoquinoline alkaloid (-)-ancistrocladinine is described.The key step was the construction of the disymmetric bi
Synthetic Approaches to the Alkaloids of the Ancistrocladaceae: Control of the Diastereoisomer Excess in the Synthesis of Axially Chiral Biaryls: a Synthesis of (-)-Ancistrocladinine
Rizzacasa, Mark A.,Sargent, Melvyn V.
, p. 278 - 280 (2007/10/02)
An attempt is made to delineate the factors which comtrol the diastereoisomeric excess in the reactions of 2,6-disubstituted phenyl Grignard reagents with the naphthyloxazoline 2; advantage is taken of the results in a synthesis of the Ancistrocladus alka
