139109-03-8

Basic information

• Product Name: Silane, (1,1-dimethylethyl)[(3,7-dimethyl-2,6-octadienyl)oxy]diphenyl-, (Z)-
• CAS NO: 139109-03-8
• Molecular Formula: C26H36OSi
• Molecular Weight: 392.657
• Mol File: 139109-03-8.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: Silane, (1,1-dimethylethyl)[(3,7-dimethyl-2,6-octadienyl)oxy]diphenyl-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (1,1-dimethylethyl)[(3,7-dimethyl-2,6-octadienyl)oxy]diphenyl-, (Z)-(139109-03-8)
• EPA Substance Registry System: Silane, (1,1-dimethylethyl)[(3,7-dimethyl-2,6-octadienyl)oxy]diphenyl-, (Z)-(139109-03-8)

Safety Data

• Hazardous Substances Data: 139109-03-8(Hazardous Substances Data)

Upstream product

• 1203571-50-9 (E)-[6-²H]-3,7-dimethylocta-2,6-dien-1-ol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 106-25-2 Nerol 
• 106-24-1 Geraniol 

Downstream Products

• 117638-13-8 (Δ^2,3E,Δ^6,7E)-1-O-tert-butyldiphenylsilyl-3,7-dimethyl-octa-2,6-dien-1,8-diol 
• 22488-05-7 geranylfarnesol 
• 145014-09-1 (Δ^2,3E,Δ^6,7E)-8-bromo-1-O-tert-butyldiphenylsilyl-3,7-dimethyl-octa-2,6-dien-1-ol 
• 412347-67-2 Methanesulfonic acid (2E,6E)-8-(tert-butyl-diphenyl-silanyloxy)-2,6-dimethyl-octa-2,6-dienyl ester 
• 145014-11-5 tert-Butyl-((2E,6E,10E,14E)-3,7,11,15,19-pentamethyl-icosa-2,6,10,14,18-pentaenyloxy)-diphenyl-silane 
• 1203571-47-4 (E)-[1,1-²H₂]-6-[(tert-butyldiphenylsilyl)oxy]-4-methylhex-4-en-1-ol 
• 1203571-49-6 (E)-[6-²H]-tert-butyl[(3,7-dimethylocta-2,6-dien-1-yl)oxy]diphenylsilane 
• 68982-81-0 (2Z,6Z,10Z)-3,7,11,15-tetramethylhexadeca-2,6,10,14-tetraen-1-yl phosphate 
• 5905-42-0 betulaprenol-8 
• 1056289-79-2 (2Z,6Z,10Z,14Z)-9-(benzenesulfonyl)-1-(tert-butyldiphenylsilyloxy)-16-chloro-3,7,11,15-tetramethylhexadeca-2,6,10,14-tetraene 
• 1056288-48-2 (2Z,6Z)-1-(tert-butyldiphenylsilyloxy)-8-chloro-3,7-dimethylocta-2,6-diene 

Relevant articles and documents

BIOSYNTHESIS OF CHEMICALLY DIVERSIFIED NON-NATURAL TERPENE PRODUCTS

The disclosure relates to compounds of the formulae (l)-(IV) and their use as substrates for making terpenoids. New substrates for terpene biosynthesis and methods for making new types of terpenes are described herein. Diterpenes occupy a unique molecular

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A process for the production of a glycoconjugate by N-glycosylation of a protein or peptide comprising the sequence D/E-X-N-X-S/T, wherein each X is the same or different and is any natural amino acid other than proline, wherein the process comprises reacting the protein or peptide with a polyisoprenyl pyrophosphate of formula (I), or a salt thereof, in the presence of PglB: (I) to produce the glycoconjugate comprising the protein or peptide having a saccharide [SI] linked to the asparagine in the sequence D/E-X-N-X-S/T. Polyisoprenylpyrophosphates used as substrates in the biocatalytic process are also provided, as well as certain glycoconjugates.

Synthesis of isotopically labelled oligoprenyl diphosphates and their application in mechanistic investigations of terpene cyclases

A flexible, efficient and robust method for the synthesis of isotopically labelled oligoprenyl diphosphates was developed. The method makes use of just a few building blocks (acetone, triethyl phosphonoacetate, and ethyl acetoacetate) from which several i