412347-67-2

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 139109-03-8 tert-butyl ({[(2E)-3,7-dimethylocta-2,6-dien-1-yl]oxy})diphenylsilane 
• 106-24-1 Geraniol 
• 117638-13-8 (Δ^2,3E,Δ^6,7E)-1-O-tert-butyldiphenylsilyl-3,7-dimethyl-octa-2,6-dien-1,8-diol 
• 124-63-0 methanesulfonyl chloride 

Downstream Products

• 145014-10-4 (2E,6E,10E)-1-tert-butyldiphenylsiloxy-3,7,11,15-tetramethylhexadeca-2,6,10,14-tetraene 
• 22488-05-7 geranylfarnesol 
• 145014-09-1 (Δ^2,3E,Δ^6,7E)-8-bromo-1-O-tert-butyldiphenylsilyl-3,7-dimethyl-octa-2,6-dien-1-ol 

Relevant academic research and scientific papers

A study of oligoprenyl coupling reactions with allylic stannanes

(matrix presented) AII-E or E,Z,E-oligoprenols may be synthesized from allylic stannanes by reaction with prenyl aldehydes.

Alkene substituents for selective activation of endo-regioselective polyepoxide oxacyclizations

(Chemical equation presented) The presence of an alkenyl substituent on the terminal epoxide of a polyepoxide substrate enhances the yield of all-endo-regioselective tandem oxacyclization to trans-syn-trans-fused polycyclic ethers. For a substrate in which the epoxide and alkene functional groups are separated by two methylene substituents, a novel bromonium ion-induced endo-regioselective cyclization to bromooxepane is also described.

A simple synthetic process for the elaboration of oligoprenols by stereospecific coupling of di-, tri-, or oligoisoprenoid units

An effective method of allyl-allyl coupling which is position and stereospecific leads in a simple way to oligoprenols from E-allylic halides.